武汉工程大学 材料科学与工程学院,湖北 武汉 430205
杨晨光,男,硕士生,现从事钠离子电池磷酸盐材料研究。E-mail:543167619@qq.com
E-mail: hupu@wit.edu.cn
收稿:2022-12-22,
纸质出版:2023-08-24
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杨晨光,李贝,汤傲, 等.Mn基NASICON型钠离子电池正极材料研究进展[J].武汉大学学报(理学版),2023,69(4):432-439. DOI:10.14188/j.1671-8836.2022.0305.
YANG Chenguang,LI Bei,TANG Ao,et al.Progress on Mn-Based NASICON-Structured Cathode Materials for Sodium-Ion Batteries [J].J Wuhan Univ (Nat Sci Ed),2023,69(4):432-439. DOI:10.14188/j.1671-8836.2022.0305(Ch).
杨晨光,李贝,汤傲, 等.Mn基NASICON型钠离子电池正极材料研究进展[J].武汉大学学报(理学版),2023,69(4):432-439. DOI:10.14188/j.1671-8836.2022.0305. DOI:
YANG Chenguang,LI Bei,TANG Ao,et al.Progress on Mn-Based NASICON-Structured Cathode Materials for Sodium-Ion Batteries [J].J Wuhan Univ (Nat Sci Ed),2023,69(4):432-439. DOI:10.14188/j.1671-8836.2022.0305(Ch). DOI:
Mn基钠超离子导体(NASICON)结构材料NaMnM(PO
4
)
3
(M=V、Ti、Cr、Zr、Fe等)具有组分、结构、电位可调且成本低等特点,作为钠离子电池正极材料极具应用前景。本文系统总结了Mn基NASICON结构材料的结构特征和电化学性能,探讨了该类材料存在的关键问题以及改性途径,并提出其作为正极材料未来的研究方向。
Mn-based sodium superionic conductor (NASICON) structured materials (NaMnM(PO
4
)
3
M=V
Ti
Cr
Zr
Fe) have a promising application prospect as cathode materials for sodium-ion batteries
due to their advantages of the good adjustability of composition
structure and potential
as well as low cost. This review summarizes the structural and electrochemical characteristics of Mn-based NASICON-structured materials
then analyzes the main issues of the materials and their corresponding modification strategies
and finally suggests the future research directions of such materials as cathodes for sodium-ion batteries.
VAALMA C , BUCHHOLZ D , WEIL M , et al . A cost and resource analysis of sodium-ion batteries [J]. Nature Reviews Materials , 2018 , 3 : 1 - 11 . DOI: 10.1038/natrevmats.2018.13 http://dx.doi.org/10.1038/natrevmats.2018.13 .
SLATER M D , KIM D , LEE E , et al . Sodium‐ion batteries [J]. Advanced Functional Materials , 2013 , 23 ( 8 ): 947 - 958 . DOI: 10.1002/adfm.201200691 http://dx.doi.org/10.1002/adfm.201200691 .
HWANG J Y , MYUNG S T , SUN Y K . Sodium-ion batteries: Present and future [J]. Chemical Society Reviews , 2017 , 46 ( 12 ): 3529 - 3614 . DOI: 10.1039/c6cs00776g http://dx.doi.org/10.1039/c6cs00776g .
YABUUCHI N , KUBOTA K , DAHBI M , et al . Research development on sodium-ion batteries [J]. Chemical Reviews , 2014 , 114 ( 23 ): 11636 - 11682 . DOI: 10.1021/cr500192f http://dx.doi.org/10.1021/cr500192f .
HU P , ZOU Z Y , SUN X W , et al . Uncovering the potential of M1‐site‐activated NASICON cathodes for Zn‐ion batteries [J]. Advanced Materials , 2020 , 32 ( 14 ): 1907526 . DOI: 10.1002/adma.201907526 http://dx.doi.org/10.1002/adma.201907526 .
CHEN S Q , WU C , SHEN L F , et al . Challenges and perspectives for NASICON‐type electrode materials for advanced sodium‐ion batteries [J]. Advanced Materials , 2017 , 29 ( 48 ): 1700431 . DOI: 10.1002/adma.201700431 http://dx.doi.org/10.1002/adma.201700431 .
JIAN Z L , HU Y S , JI X L , et al . NASICON‐structured materials for energy storage [J]. Advanced Materials , 2017 , 29 ( 20 ): 1601925 . DOI: 10.1002/adma.201601925 http://dx.doi.org/10.1002/adma.201601925 .
HONG H Y P . Crystal structures and crystal chemistry in the system Na 1+ x Zr 2 Si x P 3- x O 12 [J]. Materials Research Bulletin , 1976 , 11 ( 2 ): 173 - 182 . DOI: 10.1016/0025-5408(76)90073-8 http://dx.doi.org/10.1016/0025-5408(76)90073-8 .
GOODENOUGH J B , HONG H Y P , KAFALAS J A . Fast Na + -ion transport in skeleton structures [J]. Materials Research Bulletin , 1976 , 11 ( 2 ): 203 - 220 . DOI: 10.1016/0025-5408(76)90077-5 http://dx.doi.org/10.1016/0025-5408(76)90077-5 .
CHIHARA K , KITAJOU A , GOCHEVA I D , et al . Cathode properties of Na 3 M 2 (PO 4 ) 2 F 3 [M=Ti, Fe, V] for sodium-ion batteries [J]. Journal of Power Sources , 2013 , 227 : 80 – 85 . DOI: 10.1016/j.jpowsour.2012.10.034 http://dx.doi.org/10.1016/j.jpowsour.2012.10.034 .
JIAN Z L , HAN W Z , LU X , et al . Superior electrochemical performance and storage mechanism of Na 3 V 2 (PO 4 ) 3 cathode for room‐temperature sodium‐ion batteries [J]. Advanced Energy Materials , 2013 , 3 ( 2 ): 156 - 160 . DOI: 10.1002/aenm.201200558 http://dx.doi.org/10.1002/aenm.201200558 .
SARAVANAN K , MASON C W , RUDOLA A , et al . The first report on excellent cycling stability and superior rate capability of Na 3 V 2 (PO 4 ) 3 for sodium ion batteries [J]. Advanced Energy Materials , 2013 , 3 ( 4 ): 444 - 450 . DOI: 10.1002/aenm.201200803 http://dx.doi.org/10.1002/aenm.201200803 .
ZENG X G , PENG J , GUO Y , et al . Research progress on Na 3 V 2 (PO 4 ) 3 cathode material of sodium ion battery [J]. Frontiers in Chemistry , 2020 , 8 : 635 . DOI: 10.3389/fchem.2020.00635 http://dx.doi.org/10.3389/fchem.2020.00635 .
ZHU C B , SONG K P , VAN AKEN P A , et al . Carbon-coated Na 3 V 2 (PO 4 ) 3 embedded in porous carbon matrix: An ultrafast Na-storage cathode with the potential of outperforming Li cathodes [J]. Nano Letters , 2014 , 14 ( 4 ): 2175 - 2180 . DOI: 10.1021/nl500548a http://dx.doi.org/10.1021/nl500548a .
JIANG Y , YANG Z Z , LI W H , et al . Nanoconfined carbon-coated Na 3 V 2 (PO 4 ) 3 particles in mesoporous carbon enabling ultralong cycle life for sodium-ion batteries [J]. Advanced Energy Materials , 2015 , 5 ( 10 ): 1402104 . DOI: 10.1002/aenm.201402104 http://dx.doi.org/10.1002/aenm.201402104 .
ZHANG Q , WANG W , WANG Y J , et al . Controllable construction of 3D-skeleton-carbon coated Na 3 V 2 (PO 4 ) 3 for high-performance sodium ion battery cathode [J]. Nano Energy , 2016 , 20 : 11 - 19 . DOI: 10.1016/j.nanoen.2015.12.005 http://dx.doi.org/10.1016/j.nanoen.2015.12.005 .
HU P , WANG X F , WANG T S , et al . Boron substituted Na 3 V 2 (P 1- x B x O 4 ) 3 cathode materials with enhanced performance for sodium‐ion batteries [J]. Advanced science , 2016 , 3 ( 12 ): 1600112 . DOI: 10.1002/advs.201600525 http://dx.doi.org/10.1002/advs.201600525 .
LI H , TANG H M , MA C Z , et al . Understanding the electrochemical mechanisms induced by gradient Mg 2+ distribution of Na-rich Na 3+ x V 2- x Mg x (PO 4 ) 3 /C for sodium ion batteries [J]. Chemistry of Materials , 2018 , 30 ( 8 ): 2498 - 2505 . DOI: 10.1021/acs.chemmater.7b03903 http://dx.doi.org/10.1021/acs.chemmater.7b03903 .
LI H , BAI Y , WU F , et al . Na-rich Na 3+ x V 2- x Ni x (PO 4 ) 3 /C for sodium ion batteries: Controlling the doping site and improving the electrochemical performances [J]. ACS Applied Materials & Interfaces , 2016 , 8 ( 41 ): 27779 - 27787 . DOI: 10.1021/acsami.6b09898 http://dx.doi.org/10.1021/acsami.6b09898 .
SHEN X , HAN M , SU Y , et al . Alkali metal ion induced lattice regulation for all climate NASICON-type cathode with superior Na-storage performance [J]. Nano Energy , 2023 , 114 : 108640 . DOI: 10.1016/j.nanoen.2023.108640 http://dx.doi.org/10.1016/j.nanoen.2023.108640 .
ZAKHARKIN M V , DROZHZHIN O A , TERESH-CHENKO I V , et al . Enhancing Na + extraction limit through high voltage activation of the NASICON-type Na 4 MnV(PO 4 ) 3 cathode [J]. ACS Applied Energy Materials , 2018 , 1 ( 11 ): 5842 - 5846 . DOI: 10.1021/acsaem.8b01269 http://dx.doi.org/10.1021/acsaem.8b01269 .
ZHANG J , LIU Y C , ZHAO X D , et al . A novel NASICON‐type Na 4 MnCr(PO 4 ) 3 demonstrating the energy density record of phosphate cathodes for sodium‐ion batteries [J]. Advanced Materials , 2020 , 32 ( 11 ): 1906348 . DOI: 10.1002/adma.201906348 http://dx.doi.org/10.1002/adma.201906348 .
ZHANG W , LI H X , ZHANG Z A , et al . Full activation of Mn 4+ /Mn 3+ redox in Na 4 MnCr(PO 4 ) 3 as a high‐voltage and high‐rate cathode material for sodium‐ion batteries [J]. Small , 2020 , 16 ( 25 ): 2001524 . DOI: 10.1002/smll.202001524 http://dx.doi.org/10.1002/smll.202001524 .
ZHANG H , JEONG S , QIN B S , et al . Towards high‐performance aqueous sodium‐ion batteries: Stabilizing the solid/liquid interface for NASICON‐type Na 2 VTi(PO 4 ) 3 using concentrated electrolytes [J]. ChemSusChem , 2018 , 11 ( 8 ): 1382 - 1389 . DOI: 10.1002/cssc.201800194 http://dx.doi.org/10.1002/cssc.201800194 .
WANG H B , ZHANG T R , CHEN C , et al . High-performance aqueous symmetric sodium-ion battery using NASICON-structured Na 2 VTi(PO 4 ) 3 [J]. Nano Research , 2018 , 11 ( 1 ): 490 - 498 . DO I: 10.1007/s12274-017-1657-5 http://dx.doi.org/10.1007/s12274-017-1657-5 .
GILANKAR A , MITRA A , SINGH J , et al . Investigations on different strategies towards improving the electrochemical properties of Na 2 VTi(PO 4 ) 3 for symmetrical sodium-ion batteries [J]. Journal of Alloys and Compounds , 2021 , 851 : 156813 . DOI: 10.1016/j.jallcom.2020.156813 http://dx.doi.org/10.1016/j.jallcom.2020.156813 .
GAO H C , SEYMOUR I D , XIN S , et al . Na 3 MnZr(PO 4 ) 3 : A high-voltage cathode for sodium batteries [J]. Journal of the American Chemical Society , 2018 , 140 ( 51 ): 18192 - 18199 . DOI: 10.1021/jacs.8b11388 http://dx.doi.org/10.1021/jacs.8b11388 .
CAO Y J , YANG C , LIU Y , et al . A new polyanion Na 3 Fe 2 (PO 4 )P 2 O 7 cathode with high electrochemical performance for sodium-ion batteries [J]. ACS Energy Letters , 2020 , 5 ( 12 ): 3788 - 3796 . DOI: 10.1021/acsenergylett.0c01902 http://dx.doi.org/10.1021/acsenergylett.0c01902 .
XU C L , ZHAO J M , WANG E H , et al . A novel NASICON‐typed Na 4 VMn 0.5 Fe 0.5 (PO 4 ) 3 cathode for high‐performance Na‐ion batteries [J]. Advanced Energy Materials , 2021 , 11 ( 22 ): 2100729 . DOI: 10.1002/aenm.202100729 http://dx.doi.org/10.1002/aenm.202100729 .
CHEN F , KOVRUGIN V M , DAVID R , et al . A NASICON‐type positive electrode for Na batteries with high energy density: Na 4 MnV(PO 4 ) 3 [J]. Small Methods , 2019 , 3 ( 4 ): 1800218 . DOI: 10.1002/smtd.201800218 http://dx.doi.org/10.1002/smtd.201800218 .
ZHOU W , XUE L , LÜ X , et al . Na x MV(PO 4 ) 3 (M=Mn, Fe,Ni) structure and properties for sodium extraction [J]. Nano Letters , 2016 , 16 ( 12 ): 7836 - 7841 . DOI: 10.1021/acs.nanolett.6b04044 http://dx.doi.org/10.1021/acs.nanolett.6b04044 .
ESSEHLI R , ALKHATEEB A , MAHMOUD A , et al . Optimization of the compositions of polyanionic sodium-ion battery cathode NaFe 2- x V x (PO 4 )(SO 4 ) 2 [J]. Journal of Power Sources , 2020 , 469 : 228417 . DOI: 10.1016/j.jpowsour.2020.228417 http://dx.doi.org/10.1016/j.jpowsour.2020.228417 .
FANG R H , OLCHOWKA J , PABLOS C , et al . Impact of the F - for O 2- substitution in Na 3 V 2 (PO 4 ) 2 F 3- y O y on their transport properties and electrochemical performance [J]. ACS Applied Energy Materials , 2022 , 5 ( 1 ): 1065 - 1075 . DOI: 10.1021/acsaem.1c03446 http://dx.doi.org/10.1021/acsaem.1c03446 .
GAO X Y , LIAN R Q , HE L , et al . Phase transformation, charge transfer, and ionic diffusion of Na 4 MnV(PO 4 ) 3 in sodium-ion batteries: A combined first-principles and experimental study [J]. Journal of Materials Chemistry A , 2020 , 8 ( 34 ): 17477 - 17486 . DOI: 10.1039/D0TA05929C http://dx.doi.org/10.1039/D0TA05929C .
ZHU T , HU P , WANG X P , et al . Realizing three‐electron redox reactions in NASICON‐structured Na 3 MnTi(PO 4 ) 3 for sodium‐ion batteries [J]. Advanced Energy Materials , 2019 , 9 ( 9 ): 1803436 . DOI: 10.1002/aenm.201803436 http://dx.doi.org/10.1002/aenm.201803436 .
LAVELA P , KLEE R , TIRADO J L . On the benefits of Cr substitution on Na 4 MnV(PO 4 ) 3 to improve the high voltage performance as cathode for sodium-ion batteries [J]. Journal of Power Sources , 2021 , 495 : 229811 . DOI: 10.1016/j.jpowsour.2021.229811 http://dx.doi.org/10.1016/j.jpowsour.2021.229811 .
WANG J Y , WANG Y , SEO D H , et al . A high‐energy NASICON‐type cathode material for Na‐ion batteries [J]. Advanced Energy Materials , 2020 , 10 ( 10 ): 1903968 . DOI: 10.1002/aenm.201903968 http://dx.doi.org/10.1002/aenm.201903968 .
SINGH B , WANG Z L , PARK S , et al . A chemical map of NaSICON electrode materials for sodium-ion batteries [J]. Journal of Materials Chemistry A , 2021 , 9 ( 1 ): 281 - 292 . DOI: 10.1039/d0ta10688g http://dx.doi.org/10.1039/d0ta10688g .
ZAKHARKIN M V , DROZHZHIN O A , RYAZANTSEV S V , et al . Electrochemical properties and evolution of the phase transformation behavior in the NASICON-type Na 3+ x Mn x V 2- x (PO 4 ) 3 (0≤ x ≤1) cathodes for Na-ion batteries [J]. Journal of Power Sources , 2020 , 470 : 228231 . DOI: 10.1016/j.jpowsour.2020.228231 http://dx.doi.org/10.1016/j.jpowsour.2020.228231 .
ANISHCHENKO D V , ZAKHARKIN M V , NIKITINA V A , et al . Phase boundary propagation kinetics predominately limit the rate capability of NASICON-type Na 3+ x Mn x V 2- x (PO 4 ) 3 (0≤ x ≤1) materials [J]. Electrochimica Acta , 2020 , 354 : 136761 . DOI: 10.1016/j.electacta.2020.136761 http://dx.doi.org/10.1016/j.electacta.2020.136761 .
TANG A , LIN W G , XIAO D D , et al . High rate capability achieved by reducing the miscibility gap of Na 4- x MnV(PO 4 ) 3 [J]. Inorganic Chemistry Frontiers , 2022 , 9 ( 21 ): 5454 - 5462 . DOI: 10.1039/d2qi01568d http://dx.doi.org/10.1039/d2qi01568d .
CHENG S Q , LI W N , XIAO S H , et al . Effects of calcination temperature on electrochemical properties of cathode material Na 4 MnV(PO 4 ) 3 /C synthesized by sol-gel method for sodium-ion batteries [J]. Journal of Alloys and Compounds , 2021 , 850 : 156707 . DOI: 10.1016/j.jallcom.2020.156707 http://dx.doi.org/10.1016/j.jallcom.2020.156707 .
ZHANG W , ZHANG Z A , LI H X , et al . Engineering 3D wel l-interconnected Na 4 MnV(PO 4 ) 3 facilitates ultrafast and ultrastable sodium storage [J]. ACS applied materials & interfaces , 2019 , 11 ( 39 ): 35746 - 35754 . DOI: 10.1021/acsami.9b12214 http://dx.doi.org/10.1021/acsami.9b12214 .
ZHU T , HU P , CAI C C , et al . Dual carbon decorated Na 3 MnTi(PO 4 ) 3 : A high-energy-density cathode material for sodium-ion batteries [J]. Nano Energy , 2020 , 70 : 104548 . DOI: 10.1016/j.nanoen.2020.104548 http://dx.doi.org/10.1016/j.nanoen.2020.104548 .
ZOU Z Y , LI Y J , LU Z H , et al . Mobile ions in composite solids [J]. Chemical Reviews , 2020 , 120 ( 9 ): 4169 - 4221 . DOI: 10.1021/acs.chemrev.9b00760 http://dx.doi.org/10.1021/acs.chemrev.9b00760 .
WANG Q , ZHANG M Y , ZHOU C G , et al . Concerted ion-exchange mechanism for sodium diffusion and its promotion in Na 3 V 2 (PO 4 ) 3 framework [J]. The Journal of Physical Chemistry C , 2018 , 122 ( 29 ): 16649 - 16654 . DOI: 10.1021/acs.jpcc.8b06120 http://dx.doi.org/10.1021/acs.jpcc.8b06120 .
RAJAGOPALAN R , ZHANG Z N , TANG Y G , et al . Understanding crystal structures, ion diffusion mechanisms and sodium storage behaviors of NASICON materials [J]. Energy Storage Materials , 2021 , 34 : 171 - 193 . DOI: 10.1016/j.ensm.2020.09.007 http://dx.doi.org/10.1016/j.ensm.2020.09.007 .
GHOSH S , BARMAN N , MAZUMDER M , et al . High capacity and high-rate NASICON‐Na 3.75 V 1.25 Mn 0.75 (PO 4 ) 3 cathode for Na‐ion batteries via modulating electronic and crystal structures [J]. Advanced Energy Materials , 2020 , 10 : 1902918 . DOI: 10.1002/aenm.201902918 http://dx.doi.org/10.1002/aenm.201902918 .
ZHANG J , ZHAO X D , SONG Y Z , et al . Understanding the superior sodium-ion storage in a novel Na 3.5 Mn 0.5 V 1.5 (PO 4 ) 3 cathode [J]. Energy Storage Materials , 2019 , 23 : 25 - 34 . DOI: 10.1016/j.ensm.2019.05.041 http://dx.doi.org/10.1016/j.ensm.2019.05.041 .
KUMAR P R , KHEIREDDINE A , NISAR U , et al . Na 4 MnV(PO 4 ) 3 -rGO as Advanced cathode for aqueous and non-aqueous sodium ion batteries [J]. Journal of Power Sources , 2019 , 429 : 149 - 155 . DOI: 10.1016/j.jpowsour.2019.04.080 http://dx.doi.org/10.1016/j.jpowsour.2019.04.080 .
CUI G , DDONG Q , WANG Z , et al . Achieving highly reversible and fast sodium storage of Na 4 VMn(PO 4 ) 3 /C-rGO composite with low-fraction rGO via spray-drying technique [J]. Nano Energy , 2021 , 89 : 106462 . DOI: 10.1016/j.nanoen.2021.106462 http://dx.doi.org/10.1016/j.nanoen.2021.106462 .
ZHANG W , LI H , ZHANG Z , et al . Full activation of Mn 4+ /Mn 3+ redox in Na 4 MnCr(PO 4 ) 3 as a high-voltage and high-rate cathode material for sodium-ion batteries [J]. Small , 2020 , 16 ( 25 ): 2001524 . DOI: 10.1002/smll.202001524 http://dx.doi.org/10.1002/smll.202001524 .
ZHU T , HU P , CAI C , et al . Dual carbon decorated Na 3 MnTi(PO 4 ) 3 : A high-energy-density cathode material for sodium-ion batteries [J]. Nano Energy , 2020 , 70 : 104548 . DOI: 10.1016/j.nanoen.2020.104548 http://dx.doi.org/10.1016/j.nanoen.2020.104548 .
ZHANG W , ZHANG Z , LI H , et al . Engineering 3D well-interconnected Na 4 MnV(PO 4 ) 3 facilitates ultrafast and ultrastable sodium storage [J]. ACS Applied Materials Interfaces , 2019 , 11 ( 39 ): 35746 - 35754 . DOI: 10.1021/acsami.9b12214 http://dx.doi.org/10.1021/acsami.9b12214 .
ANISHCHENKO D V , ZAKHARKIN M V , NIKTINA V A , et al . Phase boundary propagation kinetics predominately limit the rate capability of NASICON-type Na 3+ x Mn x V 2- x (PO 4 ) 3 (0≤ x ≤1) materials [J]. Electrochimica Acta , 2020 , 354 : 136761 . DOI: 10.1016/j.electacta.2020.136761 http://dx.doi.org/10.1016/j.electacta.2020.136761 .
XU C , XIAO R . ZHAO J, et al. Mn-rich phosphate cathodes for Na-ion batteries with superior rate performance[J]. ACS Energy Letters , 2021 , 7 ( 1 ): 97 - 107 . DOI: 10.1021/acsenergylett.1c02107 http://dx.doi.org/10.1021/acsenergylett.1c02107 .
ZHAO Y J , GAO X W , GAO H C , et al . Elevating energy density for sodium-ion batteries through multielectron reactions [J]. Nano Letters , 2021 , 21 ( 5 ): 2281 - 2287 . DOI: 10.1021/acs.nanolett.1c00100 http://dx.doi.org/10.1021/acs.nanolett.1c00100 .
XU C , ZHAO J , WANG E , et al . A novel NASICON-typed Na 4 VMn 0.5 Fe 0.5 (PO 4 ) 3 cathode for high erformance Na + ion Batteries [J]. Advanced Energy Materials . 2023 , 11 : 2100729 . DOI: 10.1002/aenm.202100729 http://dx.doi.org/10.1002/aenm.202100729 .
PARK S , CHOTARD J N , CARLIER D , et al . Irreversible electrochemical reaction at high voltage induced by distortion of Mn and V structural environments in Na 4 MnV(PO 4 ) 3 [J]. Chemistry of Materials , 2023 , 35 ( 8 ): 3181 - 3195 . DOI: 10.1021/acs.chemmater.2c03787 http://dx.doi.org/10.1021/acs.chemmater.2c03787 .
BURYAK N S , ANISHCHENKC D V , LEVIN E E , et al . High-voltage structural evolution and its kinetic consequences for the Na 4 MnV(PO 4 ) 3 sodium-ion battery cathode material [J]. Journal of Power Sources , 2022 , 518 : 230769 . DOI: 10.1016/j.jpowsour.2021.230769 http://dx.doi.org/10.1016/j.jpowsour.2021.230769 .
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